PREPARATION AND MOLECULAR STRUCTURE OF TRlS[(N, N, N\' , N\' - DIAMINE) L1TI-IIUMj TETRAMETHYLETHYLENE HEXAMETHYLSAMARATE(III), {[Li(TMEDA)b [Sm(CH3)6]}.THF
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Abstract:
Inc Sm(1)(TIIFh reacts with mcthylllthlUm In TIIF In the prese nce of lclram c lhyt c lhy lcn c d lamln e, TMEDA , 10 gIve 1[1 .J(l ·MI :I)A)h[Sm«('I I)61}. J'IIF. Tl1c complex has been ch;lractcnzcd hy elemenl al analyses, lit spectrum and magnetic mcasurem ent . Molecular .lOd clymsl .SruClUrc of thl! complcx hoo been determmed by a sIngle cryst .. ! X - ray diffractIOn . The crystalS arc trigonal WIth a = 16.6X4( IO)A , c = 24.946( IO)A , sp<lec group R3c, and SIX molecuies/ulll! cell. The final It v,.Ilue is 0.043 for 2.140 reneclions measured.
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Journal title
volume 2 issue 2
pages 1- 9
publication date 1994-10
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